Basic principles of ferro silicon smelting

Dec 12, 2022

The basic principle reaction formula of ferrosilicon smelting is: SiO2+C=Si+CO; the whole reaction is roughly divided into the following

four stages:

(1) SiO disproportionation reaction zone

The main reaction in this area is SiO(g)+ 2C(s)=SiC(S)+CO(g)

That is, the silicon oxide gas rising from the bottom of the furnace (various gasification zone) reacts with blue carbon to produce silicon carbide.

(2) SiC production area

The main reaction in this area is SiO2 (L) +3C(s)= SiC(S)+2CO(g)

That is, due to the temperature rise in this area, the silicon dioxide melts from a solid state to a liquid state (semi-molten state), and the reaction

The contact surface increases, and a large amount of blue carbon reacts to form silicon carbide.

(3) SiC decomposition area

The main reaction in this area is SiO2 (L) + 2SiC(S)=3Si(L)+ 2CO(g)

That is, liquid silicon dioxide and silicon carbide react to produce silicon.

(4) Various gasification areas

The main reactions in this area are

3SiO2(L) + 2SiC(S)=Si(L)+ 2CO(g)+ 4SiO(g)

That is, liquid silicon dioxide and silicon carbide react to produce silicon, silicon oxide gas and carbon monoxide gas.