How do you make ferrosilicon?

Jul 29, 2025

Ferrosilicon (FeSi) is an alloy of iron and silicon, typically containing 15% to 90% silicon. It is produced in an electric arc furnace through the carbothermic reduction of silica (SiO₂) in the presence of iron sources. Here's a step-by-step overview of the production process:

Raw Materials Required:

Silica (SiO₂) – Usually sourced from quartz or high-purity sand (≥98% SiO₂).

Iron Sources – Can be iron ore (hematite/magnetite), steel scrap, or mill scale.

Carbon Reductant – Typically coke, coal, or charcoal.

Electrodes – Graphite or carbon electrodes for arc furnace operation.

Production Process:

Raw Material Preparation:

Silica, iron sources, and carbon are crushed and mixed in precise proportions based on the desired FeSi grade (e.g., FeSi75 contains ~75% Si).

Charging the Furnace:

The mixture is fed into a submerged arc furnace (SAF), which operates at very high temperatures (1600–1800°C).

The furnace is lined with refractory materials to withstand extreme heat.

Reduction Smelting:

Electric arcs between the electrodes and the charge generate intense heat.

The key reaction is the carbothermic reduction of silica:

SiO2+2C→Si+2CO (gas)

The silicon then combines with iron to form ferrosilicon:

Fe+Si→FeSi

Impurities like Al, Ca, and P form slag.

Tapping and Refining:

Molten ferrosilicon is tapped from the furnace at intervals.

Slag is removed, and the alloy may be refined further (e.g., ladle treatment to adjust composition).

Casting and Crushing:

The molten FeSi is cast into molds or granulated (water-quenched for smaller sizes).

After cooling, it is crushed and sized for sale.

Key Considerations:

Energy Intensive: Requires ~8,000–9,000 kWh per ton of FeSi.

Environmental Controls: CO emissions are captured, and slag is recycled or disposed of safely.

Grades: Common grades include FeSi72, FeSi75 (numbers denote % Si).

Applications:

Steelmaking: Deoxidizer and alloying agent.

Foundry: Modifies cast iron properties.

Magnesium Production: Used in the Pidgeon process.

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